Hi
Proof that PVg = constant for an ideal gas undergoing an adiabatic process where g is the ration of the molar or specific heat capacities. We use molar heat capacities g = c p/cv since R = cp - cv.
First start with the differential form of first law of thermodynamics applied to an adiabatic process,
In general we showed that for any type of process (for an ideal gas)
Combining the last two equations,
Replacing the pressure using the ideal gas law, p = nRT/V
Substituting R = c p - c v and integrating both sides,
Raising both sides to the e th power we obtain,
This is a useful relation between the temperature and volume for an adiabatic process all by itself.
Using the ideal gas law we can eliminate the temperature we can convert this last equation into the form for which we are looking.
Thus we see that an adiabatic process is a polytropic process with n = g.
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