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![[Post New]](/templates/default/images/icon_minipost_new.gif) 29 Mar 2008 15:30:23 IST
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Complete the following reaction  + HNO 2  ............. Please can any one tell me the cocept and ans of this qns rates assured
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29 Mar 2008 15:41:46 IST
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Re:chem qns rates asssured
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Nitwit Blubber Odment Tweak
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29 Mar 2008 16:01:45 IST
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d product is p-nitroso,N,N-dimethyl aniline: @computer001 ur picture is not clear. since it is tertiary amine it does not undergo diazodisation. hope this helps !!!!!!!!!
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Varsha
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tomorrow is what we make it today,
so if u can dream it , u can make it .
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29 Mar 2008 16:04:58 IST
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i think u r wrong.
n click on the pic if it aint clear
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Nitwit Blubber Odment Tweak
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29 Mar 2008 16:05:50 IST
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@varshavallig: nitrosation happens only in the presence of a strong acid because then only will an NO+ ion be formed.
so i think your answer is wrong.
but if there was a strong acid like H2SO4, then your answer is right coz of the powerful +R grp N-(CH3)2 present, which is the other necessary condition for nitrosation :)
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JEE and OLYMPIA INFINATUM
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29 Mar 2008 16:31:41 IST
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it is given so in my book.
check this too:http://jchemed.chem.wisc.edu/jcesoft/cca/CCA5/MAIN/1ORGANIC/ORG14/TRAM14/D/0472625/THUMBS.HTM
!!!!!!!!!!!!!!!
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Varsha
be cool,
tomorrow is what we make it today,
so if u can dream it , u can make it .
life is an ice cream ,eat it before it melts away!!!!!!!!!
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29 Mar 2008 21:23:31 IST
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yes, but note in that link you gave me, there is the presence of HCl in the reactions..
without that HCl , the reaction wont take place as i've mentioned in my above post :)
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JEE and OLYMPIA INFINATUM
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29 Mar 2008 22:29:04 IST
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varshavallig is 100% correct...... the answer is para-nitroso-N,N-dimethyl aniline.......
HNO2 is also an acid ..... it provides H+ .........
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