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ashok_p_ap (0)

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what happens when chlorobenzene is subjected to hydrolysis?
    
sandeepramesh (1247)

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what are the condns? Nothing happens at normal temperature
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digs2digi (162)

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nucleophilic subs takes place.
m-hydroxy-chloro benzene is formed.
rate if useful
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sandeepramesh (1247)

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and can you propose the mechanism of that rn??? Ive never heard of that before!
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digs2digi (162)

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i also had never heard of it.some goiitian only told me sumtime ago..
mechanism is same as that of EAS.difference is that inplace of electrophile(like Cl+,Br+ etc) ,there is nucleophile(OH-) which attacks the intermediate at meta position where there is +ve charge.
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sandeepramesh (1247)

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I dont think so. For higher temperatures, a nucleophilic subsn of the Cl with the Oh may take place but for lower temps, i dont think there will be any rn.
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digs2digi (162)

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i didnt see the temperature.i just told that a rn is possible.
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sandeepramesh (1247)

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but i still doubt that whether the rn u mentioned is likely :) i dont think that happens
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varshavallig (800)

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definitely no,Cl is an o,p director,so no m is formed.
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sandeepramesh (1247)

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again, that may depend on the rn condns
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