| Author |
Message |
![[Post New]](/templates/default/images/icon_minipost_new.gif) 5 Apr 2008 00:32:37 IST
|
|
|
HO-CH2-CH=CH2 + HOCl ------> HO-CH2-CH-CH2-OH
I
Cl
But
CH2-CH=CH2 + HOCl --------> CH2-CH-CH2-Cl
I
OH
PLZ XPLAIN WHY ISNT 1st rx followin markonikov rule........
|
|
|
|
5 Apr 2008 00:33:10 IST
|
|
|
what ???????
edited : i dont know it ...................for me c for chemistry and c for crap .. he he 
|
_________________________
|
this reply: 0 points
(with 0 
in 0 votes ) [?]
|
|
You have to be logged on to rate
|
|
|
5 Apr 2008 00:33:20 IST
|
|
|
kya leornado
|
|
this reply: 0 points
(with 0
in 0 votes ) [?]
|
|
You have to be logged on to rate
|
|
|
5 Apr 2008 00:52:26 IST
|
|
|
somebdy reply yr......plz
|
this reply: 0 points
(with 0
in 0 votes ) [?]
|
|
You have to be logged on to rate
|
|
|
5 Apr 2008 02:36:09 IST
|
|
|
d second cmpd is wrong yaar.......pls check it.........the valencies r even not satisfied...........
|
Glitter Word Generator
|
this reply: 0 points
(with 0
in 0 votes ) [?]
|
|
You have to be logged on to rate
|
|
|
5 Apr 2008 02:42:24 IST
|
|
|
dude u have not writen things clearly but acc. to what i have understood
u r handling with an eg. for 1,4 - addition
reaction does follow markonikof rule but due to conjugate pi bonds (1 pi bond and the lone pair of e- on O2) the so obtained product rearranges to the product given by u see
|
this reply: 0 points
(with 0
in 0 votes ) [?]
|
|
You have to be logged on to rate
|
|
|
5 Apr 2008 08:40:11 IST
|
|
|
1,4 addn??? There arent even 4 positions for 1,4 addn lol
|
this reply: 0 points
(with 0
in 0 votes ) [?]
|
|
You have to be logged on to rate
|
|
|
5 Apr 2008 08:54:15 IST
|
|
|
edit your question valencies are not satisfied are you referring to allylic substitution which occurs here due to higher stability of allylic carbocation due to resonance
|
this reply: 0 points
(with 0
in 0 votes ) [?]
|
|
You have to be logged on to rate
|
|
|
5 Apr 2008 15:10:59 IST
|
|
|
plz c it now i hav edited it.......
|
this reply: 0 points
(with 0
in 0 votes ) [?]
|
|
You have to be logged on to rate
|
|
|
8 Apr 2008 04:36:32 IST
|
|
|
See in first case thereis OH group which is electron donatind causing - ve charge on terminal CH2 thus attracting OH which is + ve bt OH is absent in 2 so it follows markonikoff
remember markonikoff is not universal rule u have to see qns properly before applying it hope it helps
|
When there is no hope & everything in dark..........
World says go & Graves say come.........
So never loose hope & Try another way.........
 border="0" alt="page counter">
Website Hit Counter
|
this reply: 0 points
(with 0
in 0 votes ) [?]
|
|
You have to be logged on to rate
|
|
|
|
|
Moderation Team
![[Up]](/templates/default/images/icon_up.gif "[Up]"){kind=icon}
