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![[Post New]](/templates/default/images/icon_minipost_new.gif) 17 Mar 2007 16:32:09 IST
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why can,t gases be liquefied above critical temprature
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ARUN
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![[Post New]](/templates/default/images/icon_minipost_new.gif) 17 Mar 2007 21:08:23 IST
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Gases can be converted to liquids by compressing the gas at a suitable temperature. but it becomes more difficult to liquefy them above the critical temperature because the kinetic energies of the particles that make up the gas also increase (rem'ber KE is directly proportinal to T)
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![[Post New]](/templates/default/images/icon_minipost_new.gif) 18 Mar 2007 02:07:58 IST
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A fluid cannot be liquified above its critical temperature because heat increases the molecular motion in the fluid.
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Bipin Kumar Dubey
Chemical Dept.
IIT Kharagpur
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![[Post New]](/templates/default/images/icon_minipost_new.gif) 21 Mar 2007 13:26:19 IST
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can't v increase pressure to any magnitude
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ARUN
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![[Post New]](/templates/default/images/icon_minipost_new.gif) 21 Mar 2007 14:06:31 IST
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matter can exist in three states namely, solid, liquid and gas. Under a given set of conditions of temperature and pressure, which of these would be the most stable state of a given substance depends upon the net effect of two opposing factors. Intermolecular forces tend to keep the molecules (or atoms or ions) closer, whereas thermal energy tends to keep them apart by making them move faster. increasing temperature increases thermal energy. increasing pressure increases the intermolecular forces. But above a certain temperature called critical temperature the effect of thermal energy outweighs the effect of intermolecular forces however high the pressure may be. thus we cannot liquify a gas above its critical temperature.
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kannan kv |
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![[Post New]](/templates/default/images/icon_minipost_new.gif) 22 Mar 2007 13:23:06 IST
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AS U SAID IF PRESS INCREASES INTER MOLECULAR FORCES WHY CAN'T IT B INCREASED
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ARUN
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