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Ask iit jee aieee pet cbse icse state board community Community Discussion Question: convert phenyl acetylide to benzaldehyde
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Terminator.HCV (2)

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convert phenyl acetylide to benzaldehyde
    
Terminator.HCV (2)

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PLEASE, somebody answer this. I need this.

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ASTANAVISTA BABE,
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sagarvaze (253)

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carry out ozonolysis in presence of zn to prevent oxidation of benzaldehyde


PhCCH + O3 --> PhCHO + CO2 + H20






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Terminator.HCV (2)

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ok,,,,,,,, but won't ozonolysis of benzene take place simultaneously????????
in addition, i am also confused abt the products formed after ozonolysis of an alkyne...
please explain....

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ASTANAVISTA BABE,
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ramkumar_november (1270)

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 1. react phenyl acetylide with HgSO4/H2SO4 , we will get acetophenone..


2. do iodoform reaction we will get benzoic acid 


3. convert benzoic acid to benzoyl chloride using HCl


4. convert benzoyl chloride to benzaldehyde using rosenmund reaction


 

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Terminator.HCV (2)

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ramkumar rocks!!!!!!!!!

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ASTANAVISTA BABE,
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sandeepramesh (1247)

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just a small correction,how can you use HCl in the 3rd step? I think it should be replaced by SOCl2

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ramkumar_november (1270)

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ok use SOCl2 .....
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Terminator.HCV (2)

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yo thankx!!!!!!!!!

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