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Ask iit jee aieee pet cbse icse state board community Community Discussion Question: is CH3CHO FORMS CH3COCL WITH PCL5..........
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sandesh1 (2)

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is CH3CHO FORMS CH3COCL WITH PCL5..........
    
silverdoe (31)

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It forms geminal dihalide, The C=O is broken to form CCl2.


with PCl5 or SOCl2.


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staycoolinlife (31)

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Yes, CH3CHO forms CH3COCL with PCl5. THE REACTION GOES LIKE THIS:-


CH3CHO + PCl5 GIVES CH3COCl  + PCl3 + HCl..


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silverdoe (31)

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But in NCERT text it is given gem diahlide.

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sandesh1 (2)

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i know it gives geminal dihalide . but i want to know whether it give acetyl chloride or not...............


 


 


 


plz tell me sure & with reasons ........


 


 


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