hii
U have asked for 4 distinct values and not 4 distinct real values .. rite ??
Now put x2 + x = t .. so we get
t2 + at + 4 = 0
solving we get t = (-a +

a
2 - 16)/2 , (-a -

a
2 - 16)/2
Now t shud have 2 distinct values so that further we can take 2 quadratic quations ..
So a

4, -4 ...... (1)
Now we put x
2 + x = (-a +

a
2 - 16)/2 , (-a -

a
2 - 16)/2
if (-a -

a
2 - 16)/2 = -1/4 or (-a +

a
2 - 16)/2 = -1/4 (B
2 - 4AC = 0)
then again there will be one solution for that equation as well and hence we will not get 4 distinct solutions ..
So solving we get a

65/4 ... (2)
Combining (1) and (2) we get ..
a

4, -4 , 65/4
cheers