When a semiconductor is extremely cold, almost all electrons are held tightly by individual atoms. It is hard to make them move through the material. When a semiconductor is heated(temp is increased), the heat energy knocks loose some of the electrons. These loose electrons can move through the material easily. The conductivity is higher. As more heat energy is added, more electrons break away from individual atoms, becoming free to move through the semiconductor. thus Higher temperature means greater conductivity.
However,This is NOT true for conductors. Conductors already have plenty of loose electrons. Higher temperature tends to go into these loose electrons. Adding energy makes the loose electrons move in less organized patterns. It becomes more difficult to control the direction of the electrons. This makes the conductor have less conductivity when temperature is higher