Ask iit jee aieee pet cbse icse state board community Discussion Response Post to: a green chromium compound A on fusion with alkali in presence of air forms a yellow compound B which
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Akshay (278)

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Answer given by Srijan r correct.

The reaction is

Cr2O3 (fusion with alkali) ---> CrO42-  (on acidification) --->Cr2O72-  +NH4Cl ---> (NH4)2Cr2O7 (on heating)--> Cr2O3

The chemical reactions r

2Cr2O3 + 8OH- + 3O2 --> 4CrO42- + 4H2O

2CrO42- + H2SO4 --> Cr2O72- + SO42- + H2O

Cr 2O72- + 2NH4Cl --> (NH4)2Cr2O7 +2Cl-

(NH4)2Cr2O7 (on heating) --> Cr2O3 + N2 +4H2O

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