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Ask iit jee aieee pet cbse icse state board community Discussion Response Post to: Acetoacetic ester synthesis
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waterdemon (4732)

Forum Expert Blazing goIITian

Olaaa!! Perrrfect answer. 866  [1067 rates]

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Yes Aceto acetic aster produces carboxylic acid on
 
presence of Con.KOH and also C2H5OH 
 
I am giving you the Algorithm of the reaction as it takes
 
place accordingly :
 
1)Acetacetic ester reacts with C2H5O-/C2H5OH
 
and forms CH3-CO-CH--CO-OC2H5.
 
2)The above product reacts with RX means any alkyl
 
halide to give CH3-CO-CR-CO-OC2H5.
 
Now what you asked for ..
 
3)The above product undergoes Hydrolysis in presence of
 
KOH/C2H5OH and now there is formation of "Carboxylic
 
acid".
 
The product formed is " CH3-C-OH "
                                  ll
                                  O
 
Hope you find it useful.
 
plZ rate me for my efforts.
 
Cheers!!!!!!!!!@@@@@!!!!!!!!!!

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