Stoichiometry
1.1 Mole concept & Avogadro's constant 1 Mole is equivalent to 6.023 x 1023 (Avogadro's number) units of any substance.
| Mass of 1 mole of atoms (monatomic) | Relative atomic mass in grams | Symbol used: RAM |
| Mass of 1 mole of a compound | Relative molecular mass in grams | Symbol used: Mr |
| | | |
| Number of moles = | mass |
| mass per mole |
Chemical formula is the number of each type of atom in the smallest viable unit of the substance.
Empirical formula is the simplest possible ratio of elements in a substance.
By definition the molecular formula will be an integral number of empirical formulae (x1, x2 etc)
Examples:
| Compound | Sulphuric acid | Ethane | hydrogen peroxide | propane | Ethene |
| formula | H2SO4 | C2H6 | H2O2 | C3H8 | C2H4 |
| empirical formula | H2SO4 | CH3 | HO | C3H8 | CH2 |
The simplest ratio of the number of moles of reactants and products in a chemical reaction. The balancing numbers are known as the coefficients of the reaction. Use of balancing number is essential to fulfill the law of conservation of matter. The overall set of balancing coefficients of a chemical reaction is known as the reaction stoichiometry
State symbols: (s)-Solid , (l)-liquid, (g)-gas, (aq)-aqueous solution...ie something dissolved in water. These should be included in all chemical reactions.
1.4 Mass relationships in chemical reactions The ratio of two reacting masses will be always maintained for a specific chemical reaction. These mass ratios can be found from the stoichiometry (balancing numbers) of the equation and the molar masses of the reactants and products
Limiting reagent is a term used to describe the product which will completely react leaving other reactants unused.
The reactant left behind unused at the end of a reaction is said to be in excess
Solvent - the dissolving medium (usually water)
Solute - the substance that is dissolved.
Solution - the above components when mixed together intimately so that the solid phase becomes indistinguishable from the liquid phase.
Concentration - the amount of solute per amount of solvent (units mols per dm3 (litre) or grams per litre)
Concentration = grams or moles/volume (also called Molarity)