Ask iit jee aieee pet cbse icse state board community Discussion Response Post to: Which overlap is the strongest, why? and which is the weakest, why?
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arun-rashi (1128)

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sigma bond is stronger bond than pi bond because in case of sigma bond overlapping area is more.in all sigma bond P-P >S-P>S-S >P-P pi so p-p sigma is strongest because directional nature is more ,nuclear-nuclear repulsion is less so strength is more ,in case of s-s sigma nulear repulsion is more so strength is less than p-p sigma.in all these pi bond is weakest because sidewise less overlapping.
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