The idea is to calculate the resistance between any two points on the cube, for which there are three possibilities. You can calculate the resistance across an edge of the cube, across a face diagonal or across a body diagonal. The figure below shows a schematic of the cube.

Points X and E are the ends of a cube edge, X and F give a face diagonal, and X to B gives a body diagonal. You could draw an arbitrary (DC) voltage source across X and E, X and F or X and B, and then using Kirchoff's rules (that the algebraic sum of the currents at any circuit junction must equal zero, and that the sum of the changes in potential encountered in making a complete loop equals zero), derive six equations in six unknowns for the currents in terms of the voltage and the various resistances, then solve the equations to find the total current and thus the overall resistance.
Since all the resistors are identical, however, we can take advantage of the symmetry of the cube and solve the problem in a much simpler way.
First, let us start with the resistance along a cube edge. In the photograph below, the cube is oriented to make the symmetrical arrangement easier to see. The currents going into and out of points X and Y must split equally along both resistors attached to each, and then combine equally through the bottom two pairs. So we see that the points marked ?a? must be at the same potential, and those marked ?b? must be at the same potential. If two points in a circuit are at the same potential, we may think of them as if they are connected by a wire. If we do this, we arrive at the schematic shown on the right.
Since resistors add reciprocally in parallel (that is, 1/RTOT= 1/R1+1/R2+. . .+1/Rn), if we call the value of each resistor R, then each parallel pair equals R/2, and our schematic becomes:
 | which by adding the three bottom resistors in series (RTOT= R1 + R2 + . . . + Rn) we can further simplify to: |  |
The parallel combination of R/2 and 2R gives 1/RTOT= 2/R+1/(2R) = 5R/2R2, and RTOT= (2/5)R. Added in series with the two resistors of R/2, this gives a parallel combination between X and Y of R and (7/5)R. For the edge, then, 1/RTOT= 1/R + 5/(7R) = 12R/7R2. The total resistance across the edge is thus (7/12)R