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harsha_27 (1348)

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Olaaa!! Perrrfect answer. 226  [335 rates]

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ans to the first qn is the steric hindrance
the ans to the 2nd qn. is 2*amine because in benzyl amine the lone pair on N is not involved in the +M effect as in aniline however phenyl group exerts weak +I effect on N but that effect is less than the methyl group so 2*amine has more e* density and more basic...............

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