let it fall when it makes an angle

two forces acting mgcos

and normal reaction R
at instant it falls N=0
so mgcos

=mv
2/r
as mgcos

provides centripetal force
v
2/r=gcos

conserving energy,so
mgr(1-cos

)=1/2mv
2 subs, value of v2/r
we get cos

=2/3
hope u got it
rate me if satisfied