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kbanagar (115)

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Olaaa!! Perrrfect answer. 19  [29 rates]

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STRUCTURE OF ETHYNE{C2H2
SP-HYBRIDISATION
ONE MOLECULE OF ETHYNE HAS 2 CARBON ATOMS AND 2 HYDROGEN ATOMS
THE GR &EXITED STATE OF CARBON ARE GIVEN BELOW

ground state:1s2 2s2 2p1x
2p1y   
exited state:
  1s2 2s12p1x 2p1y 2p1z

one 2s &one 2px orbital of each carbon atom undergo sp hybridisation to give 2  identical  sp-hybrid orbitals.
these r oriented  at an angle 1800 .

one hybrid orbital of each atom overlaps wit the other to form 1 c-c sigma bond . the other hybrid orbital of each carbon atom overlaps with 1s atomic orbitals of hydrogen to form 2 carbon hydrogen sigma  bonds
.
the unhybridised  2py orbital s of  both the carbon atom s over lap side ways to form 1 carbon carbon pie bond .
similarly the 2pz  orbitals  of  both the carbon  atoms overlap on sideways to  form  another carbon carbon pie bond .

COMPOSITION OF ETHYNE MOLECULE:
   Ethyne molecule consists of two C-atoms and two H-atoms (C2H2).
   NATURE OF HYBRIDIZATION:
   In ethyne molecule, each carbon atom is Sp-hybridized. Due to Sp-hybridization each carbon atom    generates two Sp-hybrid orbitals. In this way there exists four Sp-orbital in ethyne. These Sp-orbital    are arranged in linear geometry and 180o apart. Remaining py and pz unhybrid orbitals of each carbon    atom lie perpendicular to the plane of Sp-orbitals.
   SIGMA BOND FORMATION:
   One Sp-hybrid orbital of each carbon atom overlaps to produce one sigma bond between two
    C-atoms.The remaining one Sp-orbital of each C-atom overlaps with one H-atom to produce sigma    bond.
   Pi-BOND FORMATION:
   Py and Pz orbital of two carbon atoms are un-hybrid and make parallel overlapping to produce pi-bond.
   BOND LENGTH:
   The C--H bond is 1.09A and C-C is 1.2A.o.
   BOND ANGLE:
   HCC bond angle is 180o.












lighten up the darkness............

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