sign up I login
 advanced
refer a friend - earn nickels!!

Ask & Discuss Questions with Community & Experts

Moderation Team
Ask iit jee aieee pet cbse icse state board experts Discussion Response Post to: answer urgently
Forum Index -> Organic Chemistry -> View Full Question like the article? email it to a friend.  
Author Message
DON007 (1458)

Blazing goIITian

Olaaa!! Perrrfect answer. 264  [333 rates]

DON007's Avatar

total posts: 602    
offline Offline
all r not absolutely right .........................
now look,
1) inert pair effect  is reluctance of ELECTRONS of s orbital to move out of the shell ,
this is because of 2 options :
   a) s orbitals is very close to nucleus and therefore due to higher coulombic charge , they r very difficult to remove
b) higher SCREENING EFFECT CAUSED BY Selectrons than others
( understood)
 
2)
 N(SiH3)3 is planar  because SI IS PRESENT IN SECOND PERIOD , THEREFORE IT HAS D ORBITALS LEFT AND THEREFORE
LONE PAIR OF N2 r transferred to Si,
therefore planar
but in N(ch3)3  u know CARBON HAS NO D-ORBITALS LEFT...........................THERFORE PYRAMIDAL ...............
NOW U SHOULD HAVE UNDERSTOOD ..
THANKU
 

BELIEVE IN URSELF.....BECAUSE I BELIEVE IN U..............
 this reply: 2 points  (with Olaaa!! Perrrfect answer.   in 1 votes )   [?]
 
You have to be logged on to rate
  
 

Top Offers for goIITians
Correspondence Courses
Brilliant Tutorials
Narayana Institute
Aakash Institute
Classroom/Crash Courses
Narayana - Kota , Delhi , Others
Brilliant Tutorials - Class , Crash
Aakash Institute - Medical , Engg
Online Test Series
Brilliant Tutorials
Narayana Institute
Aakash Institute
Mahesh Tutorials
AMITY      Sri Chaitanya