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Ask iit jee aieee pet cbse icse state board community Discussion Response Post to: Halogen oxyacids - help !
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dev_22oct (1379)

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Olaaa!! Perrrfect answer. 253  [310 rates]

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HI is stronger acid than HCl is because of heat of ionisation which is large for HI(63.8KJ/MOL) compared to HCl(59.8kj/mol)
HEAT OF IONIZATION : the energy released in ionization of 1 MOLE HX (X=HALOGEN)
HClO3 is stronger acid than HIO3 because as the electronegativity of the central atom X decreases as we move from CL to I , the tendency of the central atom to attract the electron pair of X-O bond towards itself decreases and hence the possibility of rupture of O-H bond decreases.
 

Devendra Kumar Shukla
M.Sc physical Chemistry
Currently working in Daswani classes
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