|
|
See,in 1st one,add H+ to nitrogen in both 1st one and aniline... Now,the +ve charge in 1st one is more stabilized due to resonance with pi bonds...but dats not the case with aniline...so 1st is more basic.. In 2nd question,do similar thing...add H+ to nitrogen in both...CH3 group has +I effect..so it will tend to reduce the +ve charge intensity on N and so stabilizes it...so,methyl amine is more basic.. Am i correct??
|