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First of all note that the temperature of gas remains constant, so we have
P1V1 = P2V2
Now initially the the pressure in atmospheric pressure only, so let it be P
This is also the pressure of the gas.
So, P1V1 = PA.(90) where A is the area of the cylinder
When we start pouring the mercury the disc goes down by 32 cm leaving a space of 32 + 10 = 42 cm in the cylinder because the piston was at 90 cm initially.
So now the total pressure from outside is P + 42 which is equal to pressure of the gas. So, P2V2 = ( P + 42 ).A.58
So using P1V1 = P2V2
we get PA.(90) = ( P + 42 ).A.58
and thus solving for P we get P = 76.125 cm of mercury.