First notice few things here
1.Nucleophile is bulky, so it is a very good base than a nucleophile(just like potassium ter-butoxide).
2.The carbon attached to Br is vinylic,I mean vinylic bonds are very strong and do not break that easily.
So I think elimination predominates substitution here.
The major product will be an E2 based Dehydrohalogenation.
So H-C
C-H ,acetylene, will be the major product.