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coolriya (482)

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PLS SEE TIS  : Stability of the carbocation increases with the number of alkyl groups bonded to the charge-bearing carbon. Tertiary carbocations are more stable (and form more readily) than secondary carbocations; primary carbocations are highly unstable because, while ionized higher-order carbons are stabilized by Hyperconjugation, unsubstituted (primary) carbons are not. Therefore, reactions such as the SN1 reaction and the E1 elimination reaction normally do not occur if a primary carbocation would be formed. An exception to this occurs when there is a carbon-carbon double bond next to the ionized carbon. Such cations as allyl cation CH2=CH-CH2+ and benzyl cation C6H5-CH2+ are more stable than most other carbocations. Molecules which can form allyl or benzyl carbocations are especially reactive.



the stability of a cation is
influenced by the electronegativity
of the atom bearing the positive charge.
The more electronegative the atom the less stable
the cation
. A vinylic carbocation carries
the positive charge on an sp carbon, which is
more electronegative than an sp2
carbon of an alkyl carbocation.Therefore a primary vinylic  carbocation is less stable than a primary alkyl carbocation.


also : 

Carbocation
Stability
CH3(+) ? RCH=CH(+) < RCH2(+) ? RCH=CR(+) < R2CH(+) ? CH2=CH-CH2(+) < C6H5CH2(+)? R3C(+)
Methyl
1º-Vinyl

2º-Vinyl

1º-Allyl
1º-Benzyl


SOURCE : wikipedia ,
web.chem.ucla.edu/~harding/tutorials/cc.pdf , http://www.cem.msu.edu/~reusch/VirtualText/special1.htm


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