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sid_rocks (43)

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Olaaa!! Perrrfect answer. 7  [11 rates]

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ph-cl to ph-oH......use 1.koh,400*c,100 atm , cu catalyst....the mech is snae(substitution nucleophilic addition elimination)..


step 1)oH-&-H2O


step 2) therfore reso stabilisation.......cl- leaves(better leaving gp)


step 3)this gives benzyne formation


step 4)add oH-


step 5)then H2O,KOH,H+ leads to chelation due to moderate size of k+,  leads to the product


the high temp is b,coz phenol has partial double bond character(due to resonance)


the high pressure is implication of le-chatilier principle


info;


ahother industrial method is the raschig process


ph-cl to ph-OH


1.H2O,450*C,200atm,SiO2 catalyst


dude rate me c'mon

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