ph-cl to ph-oH......use 1.koh,400*c,100 atm , cu catalyst....the mech is snae(substitution nucleophilic addition elimination)..
step 1)oH-&-H2O
step 2) therfore reso stabilisation.......cl- leaves(better leaving gp)
step 3)this gives benzyne formation
step 4)add oH-
step 5)then H2O,KOH,H+ leads to chelation due to moderate size of k+, leads to the product
the high temp is b,coz phenol has partial double bond character(due to resonance)
the high pressure is implication of le-chatilier principle
info;
ahother industrial method is the raschig process
ph-cl to ph-OH
1.H2O,450*C,200atm,SiO2 catalyst
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