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madhusudan.chavan (1280)

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Olaaa!! Perrrfect answer. 216  [316 rates]

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Please verify is it heptane or hexane because I have not heard about hectane;


The C=O reacts with H2NNH2 (hydrazine) to form C=N-NH2


This on reaction with HgO can form Hg2O + H2O with carbon carrying a negative charge


Both the carbon atoms of the carbonyl groups( present on 1,2 carbon atoms) can now overlap to form carbon-carbon triple bond.Thus giving the product cyclohexyne(like benzyne).


You can get the mechanism of reduction of carbonyl group to CH2 by NH2NH2 in presence of basic medium (Wolf-Kishner reduction); refer to last step where a carbanion is formed, prior to formation of CH2, the carbaion on adjacent carbon can now form the triple bond.

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