HUNSDIECKER REACTION
RCOOH + NH3 -------> RCOO-NH4+---AgNO3------>RCOOAg + NH4NO3 ----Br2/ Ccl4--->RBr + CO2 +AgBr
last step follows free radical mechanism .(in which R. and CO2 is released )
this process is very efficient method 4 preparing halide from acid......................