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Ask iit jee aieee pet cbse icse state board community Discussion Response Post to: In the given reaction RCOOH+AgNO3/Br2/heat gives? ans:RBr
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ashish040191 (142)

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Olaaa!! Perrrfect answer. 18  [44 rates]

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HUNSDIECKER REACTION


 RCOOH + NH3 -------> RCOO-NH4+---AgNO3------>RCOOAg + NH4NO3   ----Br2/ Ccl4--->RBr + CO2 +AgBr


last step follows free radical mechanism .(in which R. and CO2 is released )


this process is very efficient method 4 preparing halide from acid......................

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