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mukundmadhav (460)

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Olaaa!! Perrrfect answer. 74  [119 rates]

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Intra molecular aldol condensation takes place with wiht compounds with two CHO groups
Consider CHO-CH2-CH2-CH2-CH2-CH2-CHO
Addition of base will abstract one alpha H from the carbon atom next to one of the CHO groups.
So you get CHO-CH(-)-CH2-CH2-CH2-CH2-CHO
Now this carbanion is a nucleophile, while the carbonyl carbon of the other CHO group is an electrophile
So it attacks there leaving to a ring formation
Can't draw it her so I'll describe
6 membered ring with CHO and O(-) attached to adjacent carbon atoms. Now this O- abstracts H+ from whichever base had been used initially to give the aldol product, that is 2 Methly cyclohexanol
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