Only one question at a time. For the first question In this reaction barium will react with sulfate to give barium sulfate del(G) = RTln(Q/Ksp) Here Q=(1/4)*10^-11 You have not given Ksp of BaSO4. If it is 10^-10 So del(G) = -RT*2.303log(40)
Krishna Gopal Singh
B.Tech Chemical Engg
IIT Delhi 2002
Currently doing PhD from IIT Delhi