mole and equivalent concept
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ans 3)take volume of CH4 = x N2 = y CO = z
we are burning in excess of O2 so write the reactions firstly CH4 + 2O2 -------> CO2 + 2H2O
CO + 1/2 O2 -------> CO2 N2 + O2 wont give u any reaction
we are given x + y + z = 20 ml.............a) from x ml of CH4 we will get x ml of CO2 N2 will be unreacted from z ml of CO we will get z ml of CO2 ,
KOH will react with CO2 (as KOH abosorbs carbon di oxide), so if it will abosorb , the volume will become less it is given derz a contraction of 14 ml so x+z = 14 ml...............b)
now see the reactions x ml of methane will take 2x ml of O2 (2 moles) z ml of CO will take z/2 ml of O2 (1/2 moles) total moles of O2 are given 13ml so 2x + (z/2) = 13................c)
solve these equations...... |
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