To Prove: That for free electron no conservation of momentum takes place, thus no photoelectric effect will occur.
Proof: Let us consider a free electron of mass me ,
Thus force on electron = 0
Or electron is moving with constant initial velocity = V1
Now when photon of energy = h?, is made to incident on free electron then for photo electric effect to take place the entire photon must be absorbed.
So applying conservation of Momentum before and after photon absorption we have,
h?/c + meV1 = meV2
or V1 = V2 - h?/mec ?(1)
Also applying conservation of kinetic energy we have
h? + ( ½)meV12 = (½) meV22
or V12 = V22 - 2 h?/me ?(2)
Putting (1) in (2) we obtain,
(V2 - h?/mec )2 = V22 - 2 h?/me
or V22 - 2(h?/mec) V2 + (h?/mec )2 = V22 - 2 h?/me
or - 2(h?/mec) V2 + (h?/mec )2 = - 2 h?/me
or V2 = [(h?/mec )2 + 2 h?/me] mec/2h?
or V2 = h?/2mec + c
thus, V2 > c, but velocity of electron can never be greater than speed of light so, PEE can not take place for free electron.
Conservation of SPIN NUMBER: Since before PEE for free electron the angular momentum of photon is 1 (in units of h cross) and that of electron is ½
So before PEE total angular momentum = 3/2 (in units of h cross)
After collision = ½ (as there is only electron but no photon)
So PEE can not take place for free electron.
But for bound electron the there is nucleus to conserve angular momentum.