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aankurverma (1310)

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Olaaa!! Perrrfect answer. 222  [322 rates]

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                              PREAPRATION OF DINITROGEN
 
1. By heating :
 
a) NH4NO2 (Ammonium Nitrite)  2H2O + N2
     OR
  NH4Cl + NaNO2  NaCl + H2O+ N2
 
b) (NH4)Cr2O7(Ammonium Dichromate)   2Na + 3N2   
 
c) 2NaN3  2Na + 3N2
 
d) Ba(N3)Ba + 3N2
 
2. By HNO2 :
 
a) RNH2 + HNO2  ROH + N2 + H2O
 
b) RCONH2 +  HNO  RCOOH + N2 + H2O
 
c) NH2CONH2(Urea) + 2HNO2   2N2+ CO2 +  3H2O
 
3.By oxidation of NH3 :
 
a) 2NH3 + 3CuO   3Cu + N2 + 3H2O
 
b) 2NH3 + 3PbO   3Pb + N2 + 3H2O
 
c) 2NH3 + 3HgO  3Hg + N2 + 3H2O
 
d) 2NH3 + 3NaOCl 3NaCl + N2 + 3H2O
 
e) 2NH3 + 3CaOCl2   3CaCl2 + N2 + 3H2O
 
f) 8NH3(excess) + 3Cl2   N2 + 6NH4Cl
 
g) 8NH3(excess) 3Br2   N2 + 6NH4Br
 
 
4.By using reducing of alkali metals like Na , K :-
 
a) 2NaNO2 + 6Na   4Na2O +N2
 
b) 2NaNO3 + 10Na  6Na2O + N2
 
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