h-bond is a special case of dipole-dipole interaction . H-bond involves a H atom and a highly electronegative atom (O,N,F, etc). this is how h-bonding occurs.
H-F- - - -H-F where the dotted lines are the h bonds.
dipole:
H-Cl - - - - - - - - H-Cl
this is what wikipedia says:
Hydrogen bond
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In some ways this is an especially strong example of a permanent dipole, as above. However, in the hydrogen bond, the hydrogen proton comes closer to being shared between target and donor atoms, in a
three-center two-electron bond like that in diborane. Hydrogen bonds explain the relatively high boiling points of liquids like water, ammonia, and hydrogen fluoride, compared with their heavier counterparts in the same
periodic table column.
Instantaneous dipole to induced dipole (van der Waals)
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Instantaneous dipole to induced dipole, or van der Waals forces, are the weakest, but also the most prolific?occurring between
all chemical substances. Imagine a
helium atom: At any one point in time, the
electron cloud around the (otherwise neutral) atom can be thought to be slightly imbalanced, with momentarily more negative charge on one side. This is referred to as an instantaneous dipole. This dipole, with its slight charge imbalance, may attract or repel the electrons within a neighbouring helium atom, setting up another dipole. The two atoms will be attracted for an instant, before the charge rebalances and the atoms move on.
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