Here, my friend. do it as follows :-
1. Reaction is : 2N205 -> 4NO2 + O2
2. Now, at STP, 1 mole of gas occupies 22.4 litres.
3. So, 28 litres of oxygen are occupied by 1.25 moles of O2.
4. Now, you have provided the molarity as well as the volume
of N205 present at the starting through which you can calculate the
initial amount of moles present.
5. Also, 2 moles of N2O5 gives 1 mole of oxygen.
So, 1.25 moles of oxygen is given by 2.5 moles of N2O5.
6. So, now you get the amount of N2O5 left
7. As far as rate is concerned, it is = -- ( Amount of N2O5 used ) / time