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Manipal Chemistry Syllabus-2
Engineering Entrance , MANIPAL UGET (Engg)
Manipal University Under Graduate Entrance Tests (Manipal UGET) Syllabus:
ORGANIC CHEMISTRY:
Inductive effect, Mesomeric effect and Electromeric effect with illustrations, Conversion of methane to ethane and vice versa and Methanol to ethanol and vice versa.
ISOMERISM-2:
Stereo isomerism: geometrical and optical isomerism
Geometrical isomerism-Illustration using 2-butene, maleic acid and fumaric acid as example, Optical Isomerism-Chirality, optical activity-Dextro and Laevo rotation(D and L notations).
CARBOHYDRATES:
Biological importance of carbohydrates, Classification into mono, oligo and poly saccharides. Elucidation of the open chain structure of Glucose. Haworth's structures of Glucose, Fructose, Maltose and Sucrose(elucidation not required).
OILS AND FATS:
Biological importance of oils and fats, Fatty acids-saturated, unsaturated, formation of triglycerides. Generic formula of triglycerides.Chemical nature of oils and fats-saponification, acid hydrolysis, rancidity refining of oils, hydrogenation of oils, drying oils, iodine value.
AMINO ACIDS AND PROTEINS:
Biological importance of proteins, Aminoacids - General formula
Formulae and unique feature of glycine, alanine, serine, cysteine, aspartic acid, lysine, tyrosine and proline. Zwitter ion, amphiprotic nature, isoelectric point, peptide bond, polypeptides and proteins. Denaturation of proteins, Structural features of Insulin - a natural polypeptide.
METALLURGY - 2
Physico-chemical concepts involved in the following metallurgical operations - Desilverisation of lead by Parke's process-Distribution law.
Reduction of metal oxides - Ellingham diagrams - Relative tendency to undergo oxidation in case of elements Fe Ag, Hg, Al, C. Cr, and Mg.
Blast furnace - metallurgy of iron - Reactions involved and their role, Maintenance of the temperature gradient, Role of each ingredient and Energetics
INDUSTRIALLY IMPORTANT COMPOUNDS:
Manufacture of Caustic soda by Nelson's cell Method, Ammonia by Haber's process, Sulphuric acid by Contact process and Potassium dichromate from chromite.Uses of the above compounds.
Chemical properties of Sulphuric acid: Action with metals, Dehydrating nature, Oxidation reactions and Reaction with PCI5
Chemical properties of potassium dichromate: With KOH, Oxidation reactions, formation of chromyl chloride.GROUP 18, NOBEL GASES
Applications of noble gases. Isolation of rare gases from Ramsay and Raleigh's method and separation of individual gases from noble gas mixture (Dewar's charcoal adsorption method).Preparation of Pt XeF6 by Neil Bartlett.
d - BLOCK ELEMENTS (TRANSITION ELEMENTS):
Definition. 3d series: electronic configurations, size, variable oxidation states, colour, magnetic properties, catalytic behaviour, complex formation and their interpretations.
THEORY OF DILUTE SOLUTIONS:
Vant Hoffs theory of dilute Solutions. colligative property. Examples of colligative properties-lowering of vapour pressure, elevation in boiling points, depression in freezing point and osmotic pressure.
Lowering of vapour pressure-Raoult's law (mathematical form to be assumed). Ideal and non ideal solutions (elementary idea) - measurement of relative lowering of vapour pressure-ostwald and Walker's dymnamic method. Determination of molecular mass by lowering of vapour pressure). Numerical problems.
COLLOIDS:
Introduction. Colloidal system and particle size. Types of colloidal systems. Lyophilic and lyiphobic sols, examples and differences. Preparation of sols by Bredig's arc method and peptisation. Purification of sols-dialysis and electro dialysis. Properties of sols-Tyndall effect, Brownian movement electrophoresis, origin of charge, coagulation, Hardy and Schulze rule, Protective action of sols. Gold number. Gold number of gelatin and starch. Applications of colloids. Electrical precipitation of smoke, clarification of drinking water and formation of delta.
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