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The reaction for the day Michael Addition The 1,4-addition (or conjugate addition) of resonance-stabilized carbanions. The Michael Addition is thermodynamically controlled; the reaction donors are active methylenes such as malonates and nitroalkanes, and the acceptors are activated olefins such as ?,?-unsaturated carbonyl compounds. Examples: donors acceptors Mechanism Recent Literature Ionic Liquid as Catalyst and Reaction Medium. The Dramatic Influence of a Task-Specific Ionic Liquid, [bmIm]OH, in Michael Addition of Active Methylene Compounds to Conjugated Ketones, Carboxylic Esters, and Nitriles . Diphenylprolinol Methyl Ether: A Highly E
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submitted by elastiboysai (2327 m) on 9 Feb 2008 14:29:04 IST (4 comments 121 views)
